I originally sent this in private e-mail by mistake. Will forward 
Vikki's reply shortly...

Welcome aboard, Vikki! I haven't had a chance to make your 
acquaintance before now.

I have a long time hobbyist's interest in electronics myself, so I
really appreciate your experiments and tinkering.

I think what you saw happening was the usual fluffy buildup 
and dark roughened coating on the neg and pos electrodes, 
respectively, being dislodged and falling off when the polarity 
changed.

I think Bob will encourage you to shorten the switching period to only
a minute or two, per his experiments. The faster rate doesn't let much
buildup occur before the states change so everything that's being
driven off the electrodes stays smaller and doesn't have much chance
to fall out of suspension.

I have a question:  Why are we even worried about H-bridges and 
relays, anyway? Aren't the logic outputs on a STAMP microcontroller or
CMOS logic chip thoroughly capable of sourcing *and* sinking at least
a milliamp or two?

There's nothing that says you have to use 30 volts. Folks have used
everything from a few volts on up with success. The only difference is
how quickly the stuff gets made.

Do you maybe have analog inputs for current monitoring and outputs
that also could be tricked to sink/source current if cross connected?
There's lots of possibilities there if so.

In the system I've been running lately, I limit the current to only a
couple of milliamps or so, to keep current density low enough to keep
the particle size down, per Trem Williams suggestions.

I use a simple current limiting resistor of a few kilohms in series
with my 30 volt supply. I'm not switching polarity at all, but that
would be the next step.

So why not toss a couple of resistors in series with two logic pins
that, combined, limit the output current to a milliamp or two when
they're cross-connected through the cell? Then switch 'em every minute
and see what you get.

Try pulse modulating the two digital outputs with R/C networks on them
to get an adjustable voltage to control cell current. Might be a
problem with the switching transient, but, hey, who says you can't
program a delay to let the current drop to zero before powering up the
other side?

Of course your analog outputs could do the same thing with a lower
parts count. 

Lots of possibilities, there!

Of all the low voltage ideas discussed to date, I believe that Bob's
polarity switching combined with Trem's current limiting might make a
very consistent and easy to run low voltage design. It would take
longer to make CS, but would require a *lot* less monitoring. You
would have minimal or no buildup on the electrodes and could run until
you had as much silver in the water as you wanted to. You could do
time or conductivity based shut-off with your controller as well, and
perhaps even cell current integration for total silver content.

Really deluxe stuff! It's the sort of stuff I'd like to see tried
next. Anybody's welcome to give it a shot. Let us all know what you
learn.

Be well,

Mike Devour
silver-list owner

[Mike Devour, Citizen, Patriot, Libertarian]
[[email protected]                       ]
[Speaking only for myself...              ]


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