Steve,

Are you aware of any methods to remove fluoride from city water?

Dan

On Mon, Jul 19, 2010 at 10:40 PM, Norton, Steve <stephen.nor...@ngc.com> wrote:
> This is interesting. A study has shown that silver nanoparticles completely
> remove endosulfan, malathion and chlorpyrifos from water. The mechanism of
> removal is adsorption followed by catalytic destruction. A household filter
> that uses the technology to remove pesticides from water has been developed.
>
> -       Steve N
>
> http://www.rsc.org/chemistryworld/News/2007/April/20040701.asp
>
> Pesticide filter debuts in India
>
> A domestic water filter that uses metal nanoparticles to remove dissolved
> pesticide residues is about to enter the Indian market. Its developers at
> the Indian Institute of Technology (IIT) in Chennai (formerly Madras)
> believe it is the first product of its kind in the world to be
> commercialised.
>
> Mumbai-based Eureka Forbes Limited, a company that sells water purification
> systems, is collaborating with IIT and has tested the device in the field
> for over six months. Jayachandra Reddy, a technical consultant to the
> company, expects the first 1000 units to be sold door-to-door from late May.
>
> 'Our pesticide filter is an offshoot of basic research on the chemistry of
> nanoparticles,' Thalappil Pradeep who led the team at IIT Chennai
> told Chemistry World. He and his student Sreekumaran Nair discovered in 2003
> that halocarbons such as carbon tetrachloride (CCl4) completely break down
> into metal halides and amorphous carbon upon reaction with gold and silver
> nanoparticles1.
>
> Pradeep said this prompted them to extend their study to include
> organochlorine and organophosphorous pesticides, whose presence in water is
> posing a health risk in rural India. In research funded by the Department of
> Science and Technology in New Delhi, his team found2,3 that gold and silver
> nanoparticles loaded on alumina were indeed able to completely remove
> endosulfan, malathion and chlorpyrifos - three pesticides that have been
> found at elevated levels in Indian water supplies.
>
> Use and recycle
>
> The mechanism of removal is 'adsorption followed by catalytic destruction',
> Pradeep explained. 'The chemistry occurs in a wide concentration range of
> environmental significance.' He added that tests proved silver particles
> from the filter are not released into the water. The IIT study found that
> gold particles perform better in the case of endosulfan. However, for cost
> reasons, the commercialised filters use only silver particles, which range
> in size from 60 to 80 nanometres at a concentration (on their alumina
> support) of 33 parts per million.
>
> 'Based on consumption patterns of a typical Indian household, the filter is
> designed to have enough nanomaterials to provide 6000 litres of
> pesticide-free water for one year,' Pradeep said. 'After that, the company
> will recycle the filters to recover the silver.'
>
> Use of nanoparticles for environmental remediation is an emerging area of
> research worldwide. Nanoscale iron powders had been shown to degrade other
> pesticides, including DDT and lindane4, 'and there are reports about the use
> of nanomaterials for removing arsenic, heavy metals and fluorides,' said
> Pradeep. 'But ours is the first product to hit the market,' he said.


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