----- Original Message -----
From: Hutt William J (Bill) DLPC <hut...@ncsc.navy.mil>

>      I've read many e-mails on this forum about achieved ppm, but
little on
> how the parties accomplished and confirmed their results.  It would be
nice
> to create a data base of methods in order to create a standard.

This is supposedly under way, at least I have made an initial
contribution, with more to follow as I find the time.

> I have seen a couple of e-mails which addressed using a volt-ohm-meter
> to read ppm.

>  Example:  4usec/cm = 1/250kohms;  this measurement appears to be
achieved
> by placing the VOM probes in the CS solution at a spacing of 1cm.
>
> Example2: 1ppm = 1.6usec/cm (+/- 20%);  If both examples are correct
then
> 5ppm would be equal to 5ppm X 1.6usec/cm = 8usec/cm
>  8usec/cm = 1/R = 125kohms resistance between the VOM probes which are
> spaced 1cm apart in the CS solution.

If only it were that simple...
Specific conductance is defined as consisting of a cell (portion of
solution) 1 cubic centimetre in dimension bounded on two opposing sides
by electrodes 1 cm square. So you can see that simply placing VOM probes
into the solution will not correlate (unless you know the cell constant
that these probes would develop). Also, conductivity measurement is
generally performed using an AC potential field of some 10K Hz or so to
avoid elctrolytic action and electrode polarisation.
In other words, one is better off using a cheap conductivity meter.

Concerning the examples you quote:
1.  4uS = 1/250K ohms by definition. 1S = 1/1ohm
2.  The equivalent weight of silver is 1.08 therefore the ppm as silver
ions (unless I am mistaken) is the conductivity measurement  x  1.08,
not 1.6 as someone reported. I questioned that figure when it was posted
but did not recieve a reply (may call into question the accuracy of some
commercial CS machines that have been sold).

 > If we can gather data from known ppm solutions using the above method
,a
> rough standard could be established and everyone would know about what
> strength of CS solution they have produced.
>
> Resistance measurements of  5ppm, 10ppm, 20ppm, and 30ppm  should give
a
> well rounded data base.

As explained, unless everybody uses the same conductivity (resistance)
parameters the results will not transfer from generator to generator.
Also there is a question about how reliable these results will be with
regard to the particle size of the colloid, although I have had good
correlation in my results between conductivity readings and ppm in my
clear and light yellow sols, more work needs to be done with darker
coloured CS products.

For what it is worth the specific resistance for the concentrations you
mention are:
5ppm - 215K ohms
10ppm -107.5K ohms
20ppm - 53.7K ohms
30ppm - 35.8K ohms

> I realize that their are many other factors to consider when trying to
> measure ppm.  The purpose of this e-mail is to try and establish a
standard
> by which everyone can use without purchasing some expensive high tech
> device.
>
> If a simple standard has already been established, what is it?
>
>      I would like to know if anyone has a recipe for making colloidal
silver
> salve.
>
>                                                  Thank you,
>
>                                                     BillH

Regards - Ivan.



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