Hi Roger,

I would just like to remind you, and myself, that I don't have all the
answers... but will respond to the best of knowledge, limited though
it is.

----- Original Message -----
From: <rogalt...@aol.com>

> In a message dated 00-04-25 01:33:15 EDT, you write:
>
> << Roger as I understand it, the water molecule is naturally
polarised
>  taking this arrangement  [H+] --- [O(2-)] --- [H+], ie having a
>  negatively charged oxygen head and two positively charged hydrogen
>  tails (the tails forming a ~105 deg angle).
>
> Good point Ivan. A batter way to have developed my idea would be to
have said
>  that in the presence of the charged aggregated CS particles, the
> polarization of the water molecules is enhanced.
>
>  Silver ions become hydrated and form micelles, ie are surrounded by
>  water molecules, in this case with their tails pointing out. Is
there
>  any reason to think that this is not what is happening?
>  This happens with LVDC CS also, which, if well made is every bit as
>  stable as well made HVAC CS.
>
> I have NO experience with the kind of LVDC CS that remains stable
> indefinitely.

There is plenty arround, I myself have numerous samples, including 20L
of Aug '98 vintage, which test exactly the same as the day they were
made.

>As far as silver ions are concerned, I don't believe that
> silver ions are present, and even if they were, they would be
associated with
> the NO3- anion (or perhaps you could name another -- as I said
repeatedly on
> this forum positive or negative ions DO NOT exist as separate
entities, but
> are always CLOSELY associated with ions of the opposite charge to
preserve
> local electrical neutrality) which we already know produces an
acidic pH
> (salt from a weak base, strong acid rule) ALL BY ITSELF.

I disaggree here, it is quite possible to manufacture a silver colloid
by precipitating the NO3 from a silver nitrate solution, leaving only
the silver ions in solution. The fact that the water molecules
surround the charged silver particles creates the local neutrality you
mention, at the edge of the water layer. This 'double layer' is one of
the defining features of colloidal systems, and is the basis for those
structured waters which rely on the addition of small particles
(usually silica based) as a 'template'.


>  There is probably some other reason causing the low pH reading,
>  perhaps ranging from CO2 inclusion to AgOH production, or possibly
>  faulty / inappropriate pH measuring equipment.
>
> The pH measurments for my HVAC CS sample were obtained from 3
separate and
> independent sources. In addition, I checked the "silver-list
archives" and
> found that the HVAC CS acidic pH phenomenon has been talked about
repeatedly.
> As far as CO2 is concerned, there is NO WAY that the presence of
carbonic
> acid could account for the low pH. For example, the CO2 typically
dissolved
> in rainwater could be said to be in equilibrium with the ~380 ppm of
CO2 in
> air. If you calculate the pH from this assumption you would arrive
at a pH of
> 5.6 - 5.7. Of course, you could ignore the assumption of
equilibrium, in
> which case the pH would be even higher.

Well, that is getting low and rain water has a deal of other dissolved
substances also, whereas distilled water has little of these and does
readily absorb CO2 from the atmosphere. CO2 absorption may be a
contributing factor, indeed when making pH measurements which are
lower than expected this is the first place to look.

 >As far as AgOH is concerned, you will
> have to elaborate on this topic. The HVAC CS I produce is crystal
clear.
> Where is the insoluble (and as far as I know relatively unstable
AgOH)
> hiding?

It is perfectly possible to have a colloid of an insoluble substance.
Silver itself could not be a colloid if it were soluble. AgO and AgOH
will swap around depending on the pH of the solution and may have a
very small particle size, besides which most insoluble substances are
soluble to some degree.

> Ivan: You are correct. I have NOT SHOWN that "HVAC CS  and
>  the water it is made in, is different structurally from LVDC CS and
>  the water it is made in". I have provided a working hypothesis from
which
> creative experiments should either support or negate my hypothesis.
So far,
> IMHO anyway, you have done neither.
>
> Roger Altman

Yes that's true enough, although I have tried to show that your theory
of polarised water molecules being the cause of a low pH reading to be
unlikely.
I know that free Ag+ ions exist in my CS because I could not read them
with my ISE if it were otherwise, and I would be happy to test your CS
for the same, if you foot the bill for postage to New Zealand<g>

Regards,
Ivan.


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