In a message dated 6/12/01 11:44:05 AM EST, [email protected] writes:

<< Now I am confused.  Shouldn't NaCl be neutral, and also a pretty good 
buffer?
 Why did the pH go to 8 instead of 7?
 
 Any ideas?
 
 Marshall
  >>

Marshall: I thought that in order for a compound to act as a buffer it had to 
be a salt of, say, a weak base and a strong acid (or the reverse) such as,

FeCl3 + 3H2O ----------> Fe(OH)3 + 3HCl 

not something like NaCl which is the salt of a strong acid and a strong base.

At the completion of FeCl3 hydrolysis, the pH is lowered and held constant by 
the generation of HCl.

As far as NaCl raising the pH of your water from 5 to 8, I think you have to 
take into account the impurity level in your table salt needed to effect the 
pH of water [ionization constant is 1 x 10^ -14]. How much (acidic or basic 
salt impurities do you think it takes in your table salt to shift the pH from 
5 to 8? You can calculate it using the ionization constant of water. Roger 


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