Mike, Thanks for making a substantial contribution to the art. Your results using very low current densities and a long "brew" time parallel my own. I, however, make a gallon at a time using currant limiting with as much as 1500 volts. I can't see why the "potential gradient" can have any effect on the end result. I'm not saying it doesn't, I just don't see why it should. What am I missing here? Arnold
----- Original Message ----- From: "Mike Monett" <fcue0n...@sneakemail.com> To: <silver-list@eskimo.com> Sent: Monday, June 09, 2003 10:58 PM Subject: CS>Re: $$$ perpectives > url: http://escribe.com/health/thesilverlist/m59996.html > CS>Re: $$$ perpectives > From: jrowland > Date: Mon, 9 Jun 2003 22:09:51 > > >> ...at the cathode, which is the location where misting will > >> start... > > > By the term "misting", are you inferring silver is being drawn off > > the cathode; the negative electrode? > > > jr > > Hi jr, > > No, I do not mean to imply silver is being drawn from the cathode. > My theory is the silver ions form an invisible cloud around both > electrodes. > > At the anode, they have just left and are slowly moving towards the > cathode. When they reach the cathode, they form another cloud since > hydrogen is also formed at the cathode, and there are no more > electrons available to interact with. > > The density of these clouds is directly related to the current and > voltage across the cell. > > At the anode, high current means a higher density of ions in the > immediate vicinity of the electrode. This increases the chance that > Brownian motion will push ions together until they get close enough > for the van Der Walls effect to make them stick. > > Note the term "Brownian motion" is not exactly correct, but it is > good enough for our purposes. Similarly, there are a number of > effects that together form the van Der Walls force, and which one > operates depends on the type of ion. It is OK to use van Der Walls > to describe any of these effects since they are all lumped together. > > The same effect occurs at the cathode. When the ion cloud is dense > enough, the particles become large enough to see, and form a mist. > > Usually, the mist first starts forming at the cathode. With low > current, round wires and no stirring, it forms a uniform cloud about > 1/16" thick around the wire. > > The cloud is denser than the surrounding water, so it begins slowly > falling to the bottom of the glass. It may form a stream and go out > at right angles to the rod, then disperse. > > The mist starts forming at the anode after it has already begun at > the cathode. I believe the reason for this is the field gradient > moves the ions away from the anode and towards the cathode, so the > density is greater at the cathode. > > The proof is to reverse the voltage applied to the rods. The cloud > that formed around the cathode disperses quickly without forming a > stream. It simply disappears. > > I believe stirring has the same effect. The particles still form, > but they are quickly dispersed. I believe this is why the three > methods of stirring I tried produced cs that was not very effective. > > Running at very low current reduces the density of the ion cloud. > This reduces the number of ions that are pushed together, and the > mist doesn't form until you reach very high concentrations. > > This stuff is unsuitable for drinking - it has a very strong > metallic taste and gives me an upset stomach. But it is OK to hold > in the mouth for ten minutes, then spit out. > > My current approach is to run 6 hrs at 335 uA with 3.85 sq. in. > wetted area and 425 ml of dw. This produces 7.24 Coulombs and 19 ppm > calculated. The current density is 87 uA/sq. in. > > The rods stay clean with only a trace of black stuff after wiping. > The salt test is quite strong. > > You can definitely tell it is having an effect after holding it in > the mouth. Just run your tongue along your teeth afterwards. The > teeth feel slightly rough and bits of tartar may fall off over the > next few days. You may find small cavities you never knew about. > > But if you have a sore throat from a flu just starting, it will be gone > the next day. > > Best Regards, > > Mike Monett > > > -- > The silver-list is a moderated forum for discussion of colloidal silver. > > Instructions for unsubscribing may be found at: http://silverlist.org > > To post, address your message to: silver-list@eskimo.com > > Silver-list archive: http://escribe.com/health/thesilverlist/index.html > > List maintainer: Mike Devour <mdev...@eskimo.com>