As to the content of the stomach: I apologize, that sulphuric acid in the
stomach was maybe some trash. I shall see what happenes in the stomach
exactly.
But: I still consider the silver to be pretty reactive:
1. When you leave it on the air, it turns black within some days. It´s the
matter of the hydrogen sulphide content in the air and silver sulphide
appears on the silver surfaces.
This, maybe is also answer to that, why sometimes the electrodes turn dark
during the batch process. I suppose, that dissolved gasses in the DW can
react with the electrode surface.
As I was informed, the best way to get out the gasses from the DW is to boil
it shortly before starting the batch.
Can I ask somebody who faces this problem with the electrodes colour change
to try this if it works ??????????????
2. Ocassionaly I work with plated silver material and if even I touch it
with my hand, an exact fingerprint turns dark in several minutes on the
silver surface. So, I must handle it wearing gloves. There are some
chemicals in the sweat, that silver reacts with almost instantly. It seems,
as if it is developed photographic image of my fingerprints.
3.  As to the reactions with the acids, as below: It is true, there is no
reaction with the hydrochloric acid.
If you pour  sulphuric acid over silver plate, there is but a slight
reaction, where the silver sulphate appears covering the whole surface and
as it is not soluble, it makes passivating (= insulating) layer over the
silver. Thus the more reaction is suppressed, the silver surface is
"passivated". In case of CS might the situation be quite different...
As to the fuming nitric, the silver dissolves absolutely in violent
reaction, with the sulphur nitrate resulting from this reaction.
I have asked for the above information my  friend - he´s  chemist.
So the answer to the Peter´ s question is:   It was fuming nitric what
violated your silver chain.
Pavel H.


Marshall Wrote

silver is one of the most inert metals there is, it is slightly more
reactive than gold, but
not much. You can drop it into fuming nitric, sulfuric and hydrochloric
acids
(independently) and nothing happens.

Marshal:

As a child once I try to clean a silver chain in an Ounce of the acid
tinners use to solder. The chain completely dissolved after a few minutes.

What kind of acid do You think it was?

Peter R





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