Hi Trem,

Yes, thank you very much. Your parameters are very interesting and I 
would like to study them more carefully. Can your give the exact 
volume of dw and the brew times?

You probably won't see any floaters with the vigorous stirring - they 
are very fragile and would be blown away. Also, reversing polarity 
would likely prevent any buildup.

With a starting voltage of 75 volts, you must be running fairly high 
current density. Also, this would require a discrete current source 
since no integrated current regulator I know of will handle more than 
about 36 volts between input and output. Is this true?

The high voltage seems to indicate you are running at higher current 
density than most cs generators. The Nernst diffusion layer should be 
quite dense, and there should be a lot of combination of Ag+ and OH- 
ions at both electrodes. 

This produces the neutral silver oxide particles that agglomerate and 
cause yellowing, as well as a strong Tyndall. Some of the reactions 
are:

  Ag+ + OH- --> AgOH

  AgOH + AgOH --> 2AgO + H2O

The Nernst diffusion layer must concentrate the ions to quite high 
density to allow this reaction. I have allowed a glass containing 1 
inch of 20 ppm cs to evaporate down to 1/8 inch (took weeks!), and it 
remained clear with no hint of color. 

The final ppm must have been at least 20 * 8 = 160ppm. The salt test 
showed enormous flakes of silver chloride that were visible without a 
microscope. So it takes even higher concentration than this to convert 
significant numbers of ions to the various silver oxides.

With the three nines process, the exponential current rise produces 
very density at the end of the brew which limits the ppm to 10 to 12 
or so. Using lower current density allows higher ppm, perhaps up to 
22ppm before significant yellowing starts.

So the vigorous stirring in your system may disrupt the Nernst layer 
enough to reduce the conversion to oxides, and you get no yellowing. 
This is very significant!

Mike Monett


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