Very interesting. However after some time when the filter gets clogged and
you have to wash the cloth, then what happens to the nanotubes?

Anil K Rajvanshi

On Thu, Sep 2, 2010 at 12:22 AM, Crispin Pemberton-Pigott <
[email protected]> wrote:

> Dear Friends
>
> I know many subscribers to this list are interested in development in
> general. Water purification (boiling) is a common task for stoves. With the
> looming advent of cheap electrical power from a stove, this article may of
> great interest to a few of you.
>
> It is another (and very interesting) application of a small amount of
> electricity for rural improvement.
>
> Regards
> Crispin
>
> ...from Gizmag.
>
>
> http://www.gizmag.com/water-purifying-nanofilter/16190/?utm_source=Gizmag+Subscribers&utm_campaign=bed812d73b-UA-2235360-4&utm_medium=email
>
> As their name suggests, most existing water purifying filters clean the
> water by physically trapping or filtering out bacteria. Stanford
> researchers have now developed a new kind of water purifying filter that
> isn’t really a filter at all. Instead of trapping bacteria, the new
> filter actually lets them pass right through. But, by the time they
> emerge from the filter they have been killed by an electrical field
> running through it. Not only is the new filter more than 80,000 times
> faster than existing filters, it is also low-cost, has no moving parts
> and uses very little power, which should make it particularly attractive
> for use in the developing world where it is needed most.
>
> The key to the new filter is coating the filter fabric – ordinary cotton
> – with nanotubes and silver nanowires. When an electric field is passed
> through the highly conductive “nano-coated” cotton, it kills almost all
> the bacteria passing through it. In lab tests, over 98 percent of
> Escherichia coli bacteria that were exposed to 20 volts of electricity
> in the filter for several seconds were killed. Multiple layers of fabric
> were used to make the filter 2.5 inches thick.
>
> "This really provides a new water treatment method to kill pathogens,"
> said Yi Cui, an associate professor of materials science and engineering
> at Stanford whose research team is also responsible for using
> nanomaterials to build batteries from paper. "It can easily be used in
> remote areas where people don't have access to chemical treatments such
> as chlorine."
> Speeding things up
>
> Filters that physically trap bacteria must have pore spaces small enough
> to keep the pathogens from slipping through, but that restricts the
> filters' flow rate. Since the new filter doesn't trap bacteria, it can
> have much larger pores, allowing water to speed through at a faster rate
> – about 80,000 times faster. The larger pore spaces in Cui's filter also
> keep it from getting clogged, which is a problem with filters that
> physically pull bacteria out of the water.
>
> Cui's research group teamed with that of Sarah Heilshorn, an assistant
> professor of materials science and engineering, whose group brought its
> bioengineering expertise to bear on designing the filters.
>
> Silver has long been known to have chemical properties that kill
> bacteria. "In the days before pasteurization and refrigeration, people
> would sometimes drop silver dollars into milk bottles to combat
> bacteria, or even swallow it," Heilshorn said.
>
> Cui's group knew from previous projects that carbon nanotubes were good
> electrical conductors, so the researchers reasoned the two materials in
> concert would be effective against bacteria. "This approach really takes
> silver out of the folk remedy realm and into a high-tech setting, where
> it is much more effective," Heilshorn said.
> Keeping costs down
>
> But the scientists also wanted to design the filters to be as
> inexpensive as possible. The amount of silver used for the nanowires was
> so small the cost was negligible, Cui said. Still, they needed a
> foundation material that was "cheap, widely available and chemically and
> mechanically robust." So they went with ordinary woven cotton fabric.
> "We got it at Wal-mart," Cui said.
>
> To turn their discount store cotton into a filter, they dipped it into a
> solution of carbon nanotubes, let it dry, then dipped it into the silver
> nanowire solution. They also tried mixing both nanomaterials together
> and doing a single dunk, which also worked. They let the cotton soak for
> at least a few minutes, sometimes up to 20, but that was all it took.
>
> The big advantage of the nanomaterials is that their small size makes it
> easier for them to stick to the cotton, Cui said. The nanowires range
> from 40 to 100 billionths of a meter in diameter and up to 10 millionths
> of a meter in length. The nanotubes were only a few millionths of a
> meter long and as narrow as a single billionth of a meter. Because the
> nanomaterials stick so well, the nanotubes create a smooth, continuous
> surface on the cotton fibers. The longer nanowires generally have one
> end attached with the nanotubes and the other end branching off, poking
> into the void space between cotton fibers.
>
> "With a continuous structure along the length, you can move the
> electrons very efficiently and really make the filter very conducting,"
> he said. "That means the filter requires less voltage."
> Low power
>
> The electrical current that helps do the killing is only a few
> milliamperes strong – barely enough to cause a tingling sensation in a
> person and easily supplied by a small solar panel or a couple 12-volt
> car batteries. The electrical current can also be generated from a
> stationary bicycle or by a hand-cranked device.
>
> The low electricity requirement of the new filter is another advantage
> over those that physically filter bacteria, which use electric pumps to
> force water through their tiny pores. Those pumps take a lot of
> electricity to operate, Cui said. However, the pores in the nano-filter
> are large enough that no pumping is needed – the force of gravity is
> enough to send the water speeding through.
>
> In some of the lab tests of the nano-filter, the electricity needed to
> run current through the filter was only a fifth of what a filtration
> pump would have needed to filter a comparable amount of water.
>
> Although the new filter is designed to let bacteria pass through, an
> added advantage of using the silver nanowire is that if any bacteria
> were to linger, the silver would likely kill it. This avoids biofouling,
> in which bacteria form a film on a filter. Biofouling is a common
> problem in filters that use small pores to filter out bacteria.
>
> Cui said the electricity passing through the conducting filter may also
> be altering the pH of the water near the filter surface, which could add
> to its lethality toward the bacteria.
>
> Next Cui and his team will try the filter on different types of bacteria
> and run tests using several successive filters.
>
> "With one filter, we can kill 98 percent of the bacteria," Cui said.
> "For drinking water, you don't want any live bacteria in the water, so
> we will have to use multiple filter stages."
>
> Cui is the senior author of a paper describing the research that will be
> published in an upcoming issue of Nano Letters. The paper is available
> online now.
>
>
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