Hi  Todd,

Thanks  for  the  info.  You`re  probably  right  about
the  glycerin,  but  I`m  still  going  to  keep  it  on
my  list  of  things  to  accomplish.  You  are  absolutely
right  about  the  methanol.  I  want  to  know  about
the  vacuum/ heat  extraction  method  in  more  detail,
so  if  you  have  some  good  info  I  would  appreciate
your  help.  I`m  not  sure  what  VOC  output  is
so  please  fill  me  in  on  that.

Hey,  I  really  got  a  charge  out  of  the  "King George
thing"  I`m  in  absolute  agreement !!!

Thanks,
David  Cruse
----- Original Message -----
From: "Appal Energy" <[EMAIL PROTECTED]>
To: <biofuel@yahoogroups.com>
Sent: Monday, April 30, 2001 7:51 PM
Subject: Re: [biofuel] glycerin


> > Does  anyone  know  a  process  that  can  be
> > used  to  purify  the  glycerin  produced  in  the
> > biodiesel  reaction  into  a  pure  or  high  grade
> > glycerol ?  High  grade  glycerol  has  a  much
> > better  market  value  than  the  crude ( 80-88% )
> > glycerin  you  get  with  standard  biodiesel  recipes.
>
> > David  Cruse
> .......................
> David,
>
> Here's the skinny on glycerin.
>
> To purify you will need to evaporate and distill it. The boiling point is
> above 500 Fahrenheit (read "boatloads of heat energy").
>
> To reduce the heat input, you can evaporate and distill under partial
> vacuum. You're talking pressure rated, insulated tanks, a serious boiler,
a
> major energy cost and uneconomical until you have a volume of "x" cubic
feet
> of crude to distill.
>
> And that's when you're doing it safely but on the cheap.
>
> Even then you must meet food or cosmetic grade compliance for both the
> facility and the product in order to attain the higher value of pure
> glycerin. This means initial cost to meet the standard, continual and
> rigorous testing to insure product integrity, insurance costs for
> distributing food or cosmetic grade products and costs almost ad
infinitum.
>
> Until you start producing several thousand gallons of biodiesel each week,
> the idea of refining glycerin is best left on paper or perhaps a pretty
> intense experiment. This truth really sucks, but no one can change the
> physical properties of glycerin.
>
> You could also experiment with glycerin as a furnace fuel or furnace fuel
> additive. Incomplete combustion generates Acrolein, however. It is
extremely
> toxic and dangerous. One should be up on their combustion mechanics and
> chemistry before trying this.
>
> Or, you could toy with the conversion of glycerin to ethanol. This would
be
> in the presence of the neutralized catalyst if you cannot determine a way
to
> remove it before fermentation. This may or may not affect the yeastie
> beasties, depending upon their nature.
>
> In any event, you should be recovering the alcohol from the glycerin layer
> for economic and environmental purposes. That may not seem like much, but
it
> is a start and gets you more familiar with evaporation/condensing
techniques
> if you're not already familiar. It also reduces your VOC output if the
> alcohol of choice was anything but ethanol.
>
> The working theory is that biodiesel manufacture is intended to be green.
> This is one theory that can be practical in reality if all avenues are
> addressed
>
> Todd
> Appal Energy
> [EMAIL PROTECTED]
>
>
>
> Biofuel at Journey to Forever:
> http://journeytoforever.org/biofuel.html
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>


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