on 8/8/04 6:29 AM, Guag Meister at [EMAIL PROTECTED] wrote:

> Hi all list members ;
> 
> While we are on the subject of pH,  can anyone give me
> a reasonable explanation as to why the pH of pure
> water is 7.0??  And I don't mean because it is in the
> middle of the range.
> 

pH is the negative logarithm of hydrogen ion
concentration. Pure water exists mostly as H2O,
but a very small amount of it (approx. one part
in 10 million) dissociates into a hydroxide ion
OH- and a hydrogen ion H+. If you multiply the
H+ concentration and the OH- concentration in an
aqueous solution, the product is a constant, called
the "dissociation constant", which for water has a
value of about 10 ^ -14. So pure water has an OH-
conc. of 10 ^ -7 and also an H+ conc. of 10 ^ -7.
Since the negative log of 10 ^ -7 is 7, it's called
pH7. OK so far?

Here's the interesting part --  if you add H+ (acid)
to an aqueous solution, it will combine with OH-
(making water) as required to keep the product of OH-
and H+ concentrations at a constant 10 ^ -14. At pH6,
for example, H+ is 10 ^ -6 and OH- is 10 ^ -8.
Similarly, adding OH- (base) will cause some of the
H+ to be scarfed up. At pH9, the OH- concentration
is 10 ^ -5 (100X its value in pure water), driving
the H+ concentration down to 10 ^ -9.


-K




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