I have a fresh Austin chalk cave rock ready to go in a vacuum chamber connected 
to a mass spec to measure the outgassing, which may give us some data soon. 

Joe
Sent from my iPhone

On Feb 14, 2012, at 10:25 AM, "George Veni" <gv...@nckri.org> wrote:

> "As for the origin of the CO2, I think that is still an open question. I'm
> not so sure about soils since there isn't much in central Texas. In small
> caves it could be organics. But in larger caves, I tend to favor out gassing
> from the limestone as it is dissolved by water - especially in caves that
> are connected to an underlying aquifer such as the Edwards where there is
> lots of water in continual contact with rock."
> 
> The soils are where the CO2 is stored; the actual source is plant
> respiration. It is not the only source of CO2 in cave air. The measured
> changes in soil that occur when plants become especially active, which have
> been correlated to changes in caves, show plant respiration is an important
> factor. How important remains to be better quantified because CO2 in Texas
> cave air increases not just with plant respiration but as we get into the
> season where airflow due to barometric changes decreases. Determining how
> much CO2 is outgassed from the limestone or deeper sources is something I've
> long wanted to do. I'm glad you're working on it Joe.
> 
> George 
> 
> 
> 
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