Balancing series packs is indeed important. This is why laptop batteries have 
all those pins on their connectors, and why hobby type batteries have balance 
charge connectors. Although they are different chemistries (laptop and 
16450/18650 batteries are typically Li-Ion while hobby type batteries are 
typically Li-Poly) they both have this requirement. And each chemistry has it’s 
own charge/discharge requirements. Note that within Li-Ion there are still 
different chemistries that again have their own requirements, which are 
different from LiFE which are different from A123. Be careful making blanket 
statements.

At the risk of violating my own comment above, if you are discharging to 2.5V 
*under load*, then that could be OK depending on the specific battery. If you 
are measuring 2.5V with *no load*, then that is over discharged for pretty much 
any chemistry. And there is really nothing to be gained by discharging to this 
level. 3V is considered to be a safe low level cutoff for most cases, and below 
about 3.2V there is little capacity remaining anyway. 

Over discharge and over charge both wind up plating metallic Lithium on the 
electrodes. Doing both is asking for trouble. Trickle charging a Li battery is 
also bad news as it over charges and again starts to plate out Lithium. 

Yes, you can use a power supply to charge Li batteries. But you must be using a 
current limited supply, and voltage regulated. 4.2V at say .5 to 1C should be 
fine as long as you are there to babysit. But if you forget and leave it go 
then you will be trickle charging. Do that for too long it may become a 
problem. You simply cannot treat Li batteries/cells as you did anything else.

Proper multi-chemistry Li chargers are not hard to find, nor are they horribly 
expensive. Please use one. (And not the cheapest one you can get from 
Hobby-King or eBay.)

References? Please see:
<http://powerelectronics.com/site-files/powerelectronics.com/files/archive/powerelectronics.com/portable_power_management/battery_charger_ics/804PET22li-ion-battery-life.pdf
 
<http://powerelectronics.com/site-files/powerelectronics.com/files/archive/powerelectronics.com/portable_power_management/battery_charger_ics/804PET22li-ion-battery-life.pdf>>

NFPA: 
<http://www.prba.org/wp-content/uploads/Exponent_Report_for_NFPA_-_20111.pdf 
<http://www.prba.org/wp-content/uploads/Exponent_Report_for_NFPA_-_20111.pdf>>
Sony: 
<https://cdn.sparkfun.com/datasheets/Prototyping/Lithium%20Ion%20Battery%20MSDS.pdf
 
<https://cdn.sparkfun.com/datasheets/Prototyping/Lithium%20Ion%20Battery%20MSDS.pdf>>
Panasonic: <http://actec.dk/media/wysiwyg/Actec/PDF/Li-Ion_handbook.pdf 
<http://actec.dk/media/wysiwyg/Actec/PDF/Li-Ion_handbook.pdf>>


Datasheets:
Different chemistry/application:
Li/SOCl2: 
<http://www.varta-microbattery.com/applications/mb_data/documents/sales_literature_varta/handbook_primary_lithium_cylindrical_series_er_en.pdf
 
<http://www.varta-microbattery.com/applications/mb_data/documents/sales_literature_varta/handbook_primary_lithium_cylindrical_series_er_en.pdf>>

vs:

Li-MnO2: 
<http://www.varta-microbattery.com/fileadmin/user_upload/downloads/products/lithium-rundzellen/HANDBOOK_Primary_Lithium_Cells_en.pdf
 
<http://www.varta-microbattery.com/fileadmin/user_upload/downloads/products/lithium-rundzellen/HANDBOOK_Primary_Lithium_Cells_en.pdf>>

vs:

<http://www.rosebatteries.com/pdfs/Panasonic%20CGR18650D.pdf 
<http://www.rosebatteries.com/pdfs/Panasonic%20CGR18650D.pdf>>
<http://www.rosebatteries.com/pdfs/Panasonic%20CGR18650C.pdf 
<http://www.rosebatteries.com/pdfs/Panasonic%20CGR18650C.pdf>>

Paul

> On Jan 23, 2017, at 6:47 AM, Bert Kehren via time-nuts <time-nuts@febo.com> 
> wrote:
> 
> The biggest mistake you can make if you plan to use them in series not to  
> equalize them before use. They come in different state of charge. Maybe 
> close if  from the same lot but not close enough and I do not count on the 
> equalizer. I  start with a discharge to 2.5 V and charge two at a time in 
> Parallel with a  holder that I modified. Set a power supply to 4.2 V 
> precisely and 
> charge all  batteries for that particular application with that setting.
> Bert Kehren
> 
> 

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