The problem with window probably is Compiz. You can change for Metacity (default in GNOME Fallback) in the System Settings or install gnome-shell and use mutter instead.

For install KDE version from Trisquel is very simple:

In Terminal(Ctrl+Alt+T):
sudo apt-get install triskel

After you log out and choose KDE in login screen (GDM or KDM).

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