Are we talking about two internal drives? If so, do not worry: the last installed distribution will populate GRUB's configuration with all available systems. I am not sure what happens with a USB external drive.

By the way: Gentoo can be 100% free. Not by default though. You need the "deblob" keyword in the USE variable and ACCEPT_LICENSE="@FSF-APPROVED @FSF-APPROVED-OTHER". All that can be defined in /etc/make.conf.

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