Perhaps consider installing the Guix package manager. With it you can currently install any (or all) of gcc 4.7.4, 4.8.5, 4.9.4, 5.4.0, 6.3.0 (see link below) so it would be possible to use the gcc specifically required by your program. The Guix packages are based on a rolling release model so they should always have the latest version available for the packages they currently provide. Their list of packages is still small compared to those available in the Trisquel repositories but it is growing all the time. The other advantage is you can be confident they only provide free software packages and is a much better option that some random ppa. I've recently done a fresh install of Trisquel 7 and have been using Guix almost exclusively as my package manager. For anything it doesn't have I can always fall back to the Trisquel repositories.

https://www.gnu.org/software/guix/packages/g.html

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