Vinagre is a VNC client (among other things). The remote computer needs a VNC *server*. Again GNOME's VNC server (Vino) is installed by default on the MATE edition of Trisquel 8. There must be something in the "Control Center" to enable it, or you can execute "the 'vino-preferences' command (for instance from the command prompt you get with Alt+F2).

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