Can you please check wheter you have correct rc2.d links?
They should look like this:
$ ls -l /etc/rc*/*cups*
lrwxrwxrwx 1 root root 14 2009-12-09 16:29 /etc/rc1.d/K80cups -> ../init.d/cups
lrwxrwxrwx 1 root root 14 2009-12-09 16:29 /etc/rc2.d/S50cups -> ../init.d/cups
lrwxrwxrwx 1 root root 14 2009-12-09 16:29 /etc/rc3.d/S50cups -> ../init.d/cups
lrwxrwxrwx 1 root root 14 2009-12-09 16:29 /etc/rc4.d/S50cups -> ../init.d/cups
lrwxrwxrwx 1 root root 14 2009-12-09 16:29 /etc/rc5.d/S50cups -> ../init.d/cups
** Changed in: upstart (Ubuntu)
Status: Confirmed => Incomplete
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CUPS daemon does not start when booting Lucid
https://bugs.launchpad.net/bugs/495726
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