Thanks for taking your time to report this issue and making Ubuntu better.
I took the liberty of reassigning this bug to the package gnome-session-bin 
which includes Startup Applications.
The Options tab is present in Maverick, but is missing for me as well on Natty. 
(gnome-session-bin version 2.32.1-0ubuntu12)

** Package changed: meta-gnome2 (Ubuntu) => gnome-session (Ubuntu)

** Changed in: gnome-session (Ubuntu)
       Status: New => Confirmed

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https://bugs.launchpad.net/bugs/705123

Title:
  Options tab missing from Startup Programs prefs dialog

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