ok, i have tried to reproduce the crash and it worked like this:
started the program out of the kde menu. 
i used the function: "Im Internet Finden" (i am using the german version, so it 
may be translated best with: online search structures)
searched for "Acetylcholin" and the only result i got was a structure with the 
CAS 66-23-9 
without selecting the line in the result field i clicked on the button 
"Auswählen" (Select) and so the pogram chrashes without a hint.

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xdrawchem crashes when importing a structure i've searched in the internet
https://bugs.launchpad.net/bugs/112644
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