Today I purged bumblebee and installed nvidia-prime again and found the 
solution.
The key is DO NOT REBOOT after changing video card in nvidia-settings. If you 
want to reboot right after the change, you MUST LOGOUT AND LOGIN then reboot, 
or, at least on my laptop, the discrete card will disappear from lspci and 
cannot be switched.
Purging nvidia-prime and a shutdown will recover the discrete card.

nvidia-prime 0.6.2
Ubuntu 14.04
kernel 3.13-0-24-generic
nvidia-331 331.38-0ubuntu7

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https://bugs.launchpad.net/bugs/1310023

Title:
  14.04: Nvidia Prime is unable to switch to the Nvidia card

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