No, this is not possible. You have a fundamental misunderstanding of how
email works. The "reply-to" field is part of the message content. A 550
rejection happens before the SMTP client even gets to start sending
message content. In other words, the 550 rejection occurs based on the
message envelope; the message contents are never seen by the server. You
need to fix your app so that it uses a valid envelope from address.
** Changed in: postfix (Ubuntu)
Status: New => Invalid
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https://bugs.launchpad.net/bugs/1468172
Title:
Upon 550-5.1.1 errors, send report to replyTo instead
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