I tried your code (thank you!) and saved it as
1. non-executable and owned by root
2. ending with two paragraphs (that's what I found the other .service-files to 
be like, but that maybe isn't compulsory)
3. saved it in /lib/systemd/system/powertop.service
4. created a symbolic link by doing 
   sudo cp -s /lib/systemd/system/powertop.service 
/etc/systemd/system/multi-user.target.wants/
5. then sudo systemctl enable powertop.service

Result:
"sudo systemctl start powertop.service" WORKS

BUT the question is still, why is the service not loading automatically
at startup?

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https://bugs.launchpad.net/bugs/1578171

Title:
  Powertop Fails as Systemd Service in 16.04

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