This is happening for me too, trying to burn an iso image to a blank CD-R. 
Output from Brasero -d:
(brasero:30369): GLib-GObject-CRITICAL **: g_object_set: assertion `G_IS_OBJECT 
(object)' failed

The UI says there is no space available.
It is version 0.7.1-3ubuntu1 in Hardy.

Serpentine works flawlessly on the same CD.

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Brasero does not recognize audio CD or blank CD-R
https://bugs.launchpad.net/bugs/181703
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