IANA Sysadmin but it looks like you're butting up against the reverse DNS issue.

http://www.simpledns.com/kb.aspx?kbid=1052


On Jul 21, 2011, at 5:45 PM, Wade Preston Shearer wrote:

> I have a site where visitors are making charitable donations. A receipt is 
> emailed to them. A high percentage of these email receipts are bouncing.
> 
> 
> Here is an example of diagnostic information being returned by one of the  
> rejecting email servers:
> 
> mail.orcon.net.nz #<mail.orcon.net.nz #5.0.0 smtp; 550-Verification failed 
> for <[email protected]> 550-Unrouteable address 550 Sender verify 
> failed> #SMTP#
> 
> 
> Original message headers:
> 
> http://pastie.org/2251238
> 
> 
> Why would it work about eighty percent of the time but not the other twenty? 
> Could the problem be that the mail is coming from an internal server name 
> "dmzweb11.local" instead of a public domain name?
> 
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