Um... NoClassDefFoundError sounds like, well, an unavailable class definition.
In this case, most likely the jar file containing 
org/apache/cayenne/query/Query.class .

This sounds like you need to read up on the workflow for installing web 
applications in Tomcat. In particular, how to make sure that all required jar 
files are available.
And maybe review the list of jar files required for Cayenne. That should be 
easy to find in the Cayenne docs.

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