Here is a sample from /var/log/maillog:
Dec 9 10:04:43 oacl-admin postfix/smtpd[8588]: warning: database /etc/postfix/aliases.db is older than source file /etc/postfix/aliases Dec 9 10:04:43 oacl-admin postfix/smtpd[8586]: connect from bay8-f114.bay8.hotmail.com[64.4.27.114] Dec 9 10:04:43 oacl-admin postfix/smtpd[8588]: connect from bay8-f114.bay8.hotmail.com[64.4.27.114] Dec 9 10:04:44 oacl-admin postfix/smtpd[8586]: 085E818699F: client=bay8-f114.bay8.hotmail.com[64.4.27.114] Dec 9 10:04:44 oacl-admin postfix/smtpd[8588]: 0877A1869A0: client=bay8-f114.bay8.hotmail.com[64.4.27.114] Dec 9 10:04:44 oacl-admin postfix/smtpd[8586]: 085E818699F: reject: RCPT from bay8-f114.bay8.hotmail.com[64.4.27.114]: 554 <[EMAIL PROTECTED]>: Relay access denied; from=<[EMAIL PROTECTED]> to=<[EMAIL PROTECTED]> proto=ESMTP helo=<hotmail.com> Dec 9 10:04:44 oacl-admin postfix/cleanup[8589]: 0877A1869A0: message-id=<[EMAIL PROTECTED]>
I'm not a postfix guy, I use exim, but it looks like you are denying relaying for yourself. You probably need to tweak the config to allow your subnet or your private side of your lan (or however you have it).
Also, it is whining about the aliases file being out of date. Postfix may need you to run a program to update that db file after you edit the aliases file. I think sendmail used to use newaliases -- I'm not sure what postfix users.
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