Frank, the prospect of this drift data has me salivating.  Perhaps make this 
available in a eevblog thread as well?

Sent from my iPhone

> On Aug 28, 2019, at 5:51 PM, Frank Stellmach <[email protected]> 
> wrote:
> 
> Hello Reginald,
> 
> the LTZ100 has been discussed and investigated thoroughly, over on eevblog.
> 
> https://www.eevblog.com/forum/metrology/ultra-precision-reference-ltz1000/
> 
> https://www.eevblog.com/forum/metrology/the-ltflu-(aka-sza263)-reference-zener-diode-circuit/
> 
> There you'll find chip and assembly pictures of the LTZ1000 / A, LTFLU, and 
> SZA 263 as well.
> 
> 
> A lot of speculation and investigation about the time, temperature (T.C. 
> trimming), and hysteretic drift can also be found there.
> 
> It's a very long thread, anyhow.
> 
> Spoiler: The LTZ1000A shows more hysteresis and also random dips, than the 
> LTZ1000.
> 
> 
> Then I also can recommend John R. Pickerings famous patent to mitigate 
> hysteresis effects after temperature excursions.
> 
> The timely drift of the LTZ1000 is linearly affected by the oven temperature 
> in a quite predictable manner, as you already assumed.
> This has already been investigated and quantified by P J Spreadbury in 1990 
> "The Ultra Zener .. is it a portable replacement for the Weston cell?". This 
> basic article I don't find any more on the net, but I have it in my archive.
> 
> The same has been done for the SZA263 and the LTFLU chips inside the 732A/B 
> references:
> 
> PREDICTABILITY OF SOLID STATE ZENER REFERENCES, by David Deaver, Fluke.
> 
> Myself, I have collected the relative drift data of 4 references, 2x LTZ1000, 
> 1x 1000A, 1x double SZA263, over about ten years. The first two references 
> have been running continuously over that time, the other two, only when used, 
> because these are sitting inside a 3458A, and a 5442A. All their individual 
> drift rates seem to confirm the mentioned papers.
> 
> Recently, about 2 years ago I started another 5 virgin LTZ1000s, nicely 
> showing the typical initial timely drift of < 2ppm/year @ 50°C.
> 
> If you are interested, let's discuss how to exchange these data.. I'm very 
> interested in a drift estimation model for these relative measurements, 
> equivalent to the Three Cornered Hat method of the time-nuts.
> 
> Frank
> 
> 
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