Mark Goldes sent me the following information which
has direct relevance to any scheme to harvest the
bounty of Earth's oceans for transportation fuel. 

As many of you know, Mark has been involved in
advanced alternative energy thinking for many years
prior to "Ultraconductors" and MPI. Nearly forty years
ago, his Aesop Institute was a sponsor of the wind car
mentioned recently. The Institute, founded in 1973, is
a non-profit tax exempt organization with the goal of
finding alternatives to fossil and uranium fuels.

BTW if any vortician out there knows of a good
candidate billionaire (i.e. the rare one with a social
conscience) - like the inimitable Richard Branson -
and which far-sighted-funder now sees the wisdom of
investing in advanced alternative energy projects,
like the one we are tossing around this week on
vortex, please have them contact Mark directly. 

Anyway, the new twist on the conversion of sargassum
into gasoline comes from George Huber of the
University of Massachusetts, Amherst. It is a
revolutionary method for making "green gasoline" from
cellulose: basically any sort of wood or grass... I
see no good reason why the same process would not be
ideal for ocean-derived forms of biomass.

Results of Huber's research were published in the
April 2008 issue of ChemSusChem, a publication devoted
to environmentally-sound chemistry. "Breaking the
Chemical and Engineering Barriers to Lignocellulosic
Biofuels,"

http://www.ecs.umass.edu/biofuels/Images/Roadmap2-08.pdf

"We've proven this method on a small scale in the
lab," says Huber, "but we need to make further
improvements and prove it on a large scale before it's
going to be economically viable."

Huber's method is a one-step conversion method,
whereas other processes like fermentation takes
several or dozens of steps.  The new catalytic
technique involves a special reactor, in which the
feedstock undergoes "catalytic fast pyrolysis" the
rapid heating to 600 degrees centigrade followed by
quick cooling. By adding zeolite catalysts to this
process, gasoline range hydrocarbons can be directly
produced from cellulose "within sixty seconds."

With cellulosic ethanol, your residence time is five
to ten days, which means you need to have a much
larger reactor for the same output and possibly could
not do this onboard the harvesting vessel itself.

With the one-step process, conversion could probably
be accomplished 24/7, and immediately after harvesting
and dewatering, and in series so that feedstock is not
stored- only finished product (gasoline for instance).


As any sailors may appreciate, the available space
onboard even a large catamaran is limited due to the
narrow hulls. Here is a smaller version of what a ship
might look like without the harvesting apparatus
between the hulls:

http://en.wikipedia.org/wiki/Planet_class_research_ship

All of this varied information, none of it
particularly unique (since even the Huber pyrolysis
process has been known in prior art) is starting to
come together into a highly "doable" package for one
near term solution to a sustainable and carbon-neutral
future...

Jones




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