I wrote:

All of the metals above appear to have low work functions. What is meant by
> "electron-donor" in this context appears to be that they're hot cathodes.
> ...
>

Also note that some of the metals in the list are radioactive, so they or
their daughters will give off alphas or betas or fission into prompt
particles.  The alphas and prompt particles will cause all kinds of
excitation in the electronic structure.

Eric

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