Hi all,


I am trying to refine a protein complex structure using Xplor-NIH that has
already been calculated using CYANA. Here this complex consists of the
first chain as protein and second chain as a peptide which is having
modified residues (phosphorylated Thr: TPO, phosphorylated Ser: SEP,
acetylated N-term: ACE and amidated C-term: CTN).



As I understood correctly by looking at the topology file, Xplor-NIH
patches the phosphate group onto already existing residues in order to
change into the phosphorylated residue. This works well when you are
starting the structure calculation. Now I am wondering about the refinement
of an existing structure that already has modified residues in it.

 I have the following questions regarding the Xplor-NIH refinement of this
system:

1.     For refinement, should I need to incorporate the modified residues
(define new residues i.e. TPO, SEP similar to ACE) in the topology file
(protein-1.0.top)? or change these residues in my input files to
conventional residues and at the end put the phosphate group (I mean use
the same method as calculating the structure).

2.     If I am going to define these residues, how one would calculate the
charge and masses associated with additional atoms.



Much appreciation in advance for any help!

-- 
Best Regards,
Karuna Dixit
Postdoctoral Research Associate

Department of Biochemistry & Biophysics

Texas A&M University

Email: [email protected]

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