Hi John,

Totally agree with you about the confidence level and what people SHOULD be 
doing.


However, I am uncomfortable with CF becoming a tool to force those who have 
quoted at standard conditions and used the existing Standard Name rework their 
data. However, should a formal approach from a recognised authority in the 
carbonate chemistry community be made to CF then my comfort level might rise 
somewhat. Then it is they who is forcing the change, not CF.


Cheers, Roy.


Please note that I partially retired on 01/11/2015. I am now only working 7.5 
hours a week and can only guarantee e-mail response on Wednesdays, my day in 
the office. All vocabulary queries should be sent to enquir...@bodc.ac.uk. 
Please also use this e-mail if your requirement is urgent.


________________________________
From: CF-metadata <cf-metadata-boun...@cgd.ucar.edu> on behalf of John Dunne - 
NOAA Federal <john.du...@noaa.gov>
Sent: 08 June 2017 18:58
To: Matthias Tuma
Cc: cf-metadata@cgd.ucar.edu
Subject: Re: [CF-metadata] Sea water pH values: at standard or in-situ 
conditions?

Hi Matthias,

I'm going to have to go with in-situ, unless someone can correct me otherwise.  
I'm 86.33% confident, however.  I have been looking at Jim Orr's documentation 
(http://www.geosci-model-dev-discuss.net/gmd-2016-155/gmd-2016-155.pdf), and it 
cites:
Biogeochemical protocols and diagnostics for the CMIP6 
...<http://www.geosci-model-dev-discuss.net/gmd-2016-155/gmd-2016-155.pdf>
www.geosci-model-dev-discuss.net
Biogeochemical protocols and diagnostics for the CMIP6 Ocean Model 
Intercomparison Project (OMIP) James C. Orr 1, Raymond G. Najjar 2, Olivier 
Aumont 3, Laurent Bopp ...




Dickson, A. G., Sabine, C. L., and Christian, J. R.: Guide to best practices 
for ocean CO2 measurements, , PICES Special Publication 3, 191
pp., http://aquaticcommons.org/1443/, 2007.

[http://aquaticcommons.org/1443/1.haspreviewThumbnailVersion/Guide_all_in_one.pdf]<http://aquaticcommons.org/1443/>

Guide to best practices for ocean CO2 measurements 
...<http://aquaticcommons.org/1443/>
aquaticcommons.org
Item Type: Monograph or Serial Issue Title: Guide to best practices for ocean 
CO2 measurements: Personal Creator/Author:


which gives the calculations for pH on the total scale in SOP6a and SOP6b as a 
function of insitu T as a variable.  Also, I would argue from an environmental 
science perspective that we *should* be posting the insitu variable.

Hope that helps! John





On Thu, Jun 8, 2017 at 5:56 AM, Matthias Tuma 
<mt...@wmo.int<mailto:mt...@wmo.int>> wrote:
Hello all,

we had a question come up for the "sea_water_ph_reported_on_total_scale" 
standard name: it appears that for some communities, in particular on the 
measurement side, pH would regularly be reported only after first having 
converted to its equivalent at standard conditions (25C, 0dbar). In other 
communities, pH would most regularly be reported at in-situ conditions 
(temperature and pressure at actual measurement spot).

While we assume that the CF conventions would implicitly assume values to be 
reported at in-situ conditions (i.e., the latter variant), my two questions are:
1) whether someone can confirm this, to be 100% certain?, and
2) whether adding a few according clarifying words to the description would be 
seen as useful?

Thanks and best,
Matthias

--
Matthias Tuma
WCRP Junior Professional Officer
c/o WMO
7bis, avenue de la Paix
Case postale 2300
CH-1211 Geneva 2
Switzerland
Tel: +41 22 730 8217<tel:+41%2022%20730%2082%2017>
Fax: +41 22 730 8036<tel:+41%2022%20730%2080%2036>
Email: mt...@wmo.int<mailto:mt...@wmo.int>
http://www.wcrp-climate.org

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