There is a handy application (perhaps more than one) for doing location-aware events, MarcoPolo, which can trigger things like changing the default printer based on available Wi-Fi networks.

One could write an AppleScript which would check for an instance of Adium -- if one exists, use AppleScript to gracefully change the profile; if not, just rewrite some default value for which profile to load the next time it's launched.

Does this satisfy both parties?

-- Ryan

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