On Saturday 21 November 2009, Jeshua Lacock wrote:
>On Nov 21, 2009, at 3:03 AM, Erik Christiansen wrote:
>> On Fri, Nov 20, 2009 at 05:10:18PM +0000, Leslie Newell wrote:
>>> Carbon dioxide is 66% oxygen (CO2). As aluminum is very active it
>>> will
>>> strip oxygen out of the CO2. That is also the reason why you should
>>> never use a CO2 fire extinguisher on magnesium fires.
>>
>> However, it is extensively used in fire extinguishers precisely
>> because
>> it does not give up its oxygen even at hundreds of degrees C. I'm not
>> sure of how many thousand degrees magnesium burns at, but it is more
>> than 1500, because thermite (magnesium and iron oxide) combustion
>> melts
>> the iron produced by the reduction of the iron oxide.
>
>Correction: "Thermite" is actually a name brand which is a mixture of
>aluminum and iron oxide.
>
>Generically speaking, Thermite is referred to an "aluminothermic"
>reaction. It is aluminum's high infinity for oxygen that strips the
>oxygen away from the iron oxide.

s/infinity/affinity :)

>I am sure you could also burn (exothermic reaction) magnesium with
>iron oxide, however, that would result in such rapid combustion it
>would cause an explosion.
>
>I have actually casted iron, steel, nickel, chromium, ferrotitanium,
>and even titanium using aluminothermic reactions (you use the oxide
>for the metal that you want - like titanium dioxide for titanium). It
>is fascinating stuff!
>
>Note that titanium dioxide takes a great deal more energy to sustain
>an exothermic reaction compared to iron oxide, so the use of a
>catalyst is required.

Interesting Jeshua, and the catalyst used was?

>
>Cheers,
>
>Jeshua Lacock
>Founder/Programmer
>3DTOPO Incorporated
><http://3DTOPO.com>
>Phone: 208.462.4171

-- 
Cheers, Gene
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