I have been experimenting with copper in order to make durable memorial 
signs. I treat a polished piece of sheet copper (or thicker) just like a 
PCB: degrease, spray photoresist, expose with laser printer foil on it 
to UV lamp, develop in 0.8% NaOH solution, etch in concentrated FeCl3 
solution. Etch hard and long, until fine details start to disappear. 
FeCl3 etches in depth five times faster than horizontally. Then rinse 
and put it in a very, very light solution of K2S (one little crystal in 
a few liters of water). This is potassium sulphide, called sulphur liver 
in German. It stinks and it's used for medical baths and may be bought 
in pharmacies. The solution must be just slightly yellow. This will turn 
the etched surface into insoluble, deep black copper sulphide CuS. The 
etching leaves a matte surface so the black will be accordingly dull. 
Agitate with soft brush. Higher concentrated K2S solution will cause the 
developing CuS to come off in thin layers, making an stainy, uneven 
colour distribution. As soon as the black color is reached (work with 
good lighting!), rinse, dry and remove photoresist. You have a shiny 
copper pattern on dull black background. This works also with brass and 
maybe (didn't try) with alpacca or some other silvery copper alloy to 
make good contrast.

Peter


andy pugh schrieb:
> On 8 January 2012 14:59, Joachim Franek <joachim.fra...@pibf.de> wrote:
>
>   
>> A temperature treatment of the lacquer
>> at 190°C will result in durable inscriptions or graphics having a blackish-
>> brown color
>>     
>
> It is worth remembering, though in my case I was much more concerned
> about reflectivity than colour. A black/brown shiny layer would not
> work.
>
>   


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