On Mon, Sep 24, 2012 at 2:59 PM, Peter Blodow <[email protected]> wrote:
> once upon a time we had a strange incident of this type at my company's
> radioactive labs: a fire started in a locked metal cabinet, where tools
> etc. were kept, having started from an oily piece of rug for cleaning
> machinery. Nobody had opened that cabinet for weeks since it contained
> tools and material only needed for the half year service of those
> nuclear devices (radiation sources) in the laboratory hall. We found out
> that certain oil sorts can ignite by themselves, independent of
> reaching  their ignition point, and even if this temperature was not
> reached by far. No idea of the circumstances, we guessd at catalytic
> action of some sort, e.g. nickel plated surfaces (nickel acts as a
> catalyst) in the vicinity or something similar. What we learned: be
> careful, discard oily rugs right away as soon as they are not used any more!
>

The oiled rags are famous for catching fire. The cause is exothermic
oil-air reaction, which mostly affects the types of oil used in
woodworking for staining and finish work (lineseed, tung, etc).Their
purpose in life is polymerization when exposed to air; apparently some
oils also oxidize exothermally. Now, the machine oil shouldn't do
either of those things, but maybe Don had some polluted oil---although
he's normally pretty by-the-book, careful guy.

http://www.statefundca.com/safety/safetymeeting/SafetyMeetingArticle.aspx?ArticleID=118

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