Integral conversion of heat into mechanical work and other absurdities
in thermodynamics

The text analysis some possibilities of increasing the yields of
combustions for thermal engines and in the same time, questions the
possibility of bulk transformation of heat into mechanical work.
The heat transformation into mechanical work is a favourite subject of
discussions and it seems that subject becomes more a philosophical
debate instead of a scientific one.
It is known that 80% of world electric energy is produced by burning
of combustible materials (coal, petrol etc) and the consequences of
this activity are becoming more evident in pollution, climate change
etc. Terrestrial and maritime transports have their part of
contribution to this stress on Earth systems. Therefore this
discussion is important not only for physicists, but for politicians
too.
In the text, some simple ideas are advanced and it ca be demonstrated
that yield of actual combustion process can be at lest doubled in
absence of any political arrangement. As consequence this increase in
yield can have as result a greater quantity of electric energy
production with a diminishing of secondary effects on Earth
ecosystem.
The text analyses some patents where water is added as emulsion or
directly injected into an engine cylinder in order to increase the
yield. From orthodox thermodynamic point of view this is an absurdity.
Because only a weird man can think that adding water to a combustible
material can increase the mechanical work, when in fact the combustion
power decreases! But the situation is not like that.
Then a new improved Rankin cycle is proposed in order to boost the
yield of   a thermoelectric factory.
More than that, it is proposed an experiment where entire quantity of
heat produced into a chemical reaction is transformed into mechanical
work. The experiment is very simple. A mixture of methane and air is
combusted into a recipient kept at -80°C and having a thick layer of
solid CO2 on the internal part of recipient’s walls. In this way, hot
gases resulted into reaction, produce sublimation of CO2 (at -79°C),
and the generated gas increase the pressure into system and force a
mechanical piston to slide to right. Assuming the layer of CO2 is
thick enough, as far the temperature of gases inside recipient is
greater then -79°C, there will be a continuous sublimation of gas
molecules, without heat loss outside system.
 More than that, this incipient engine works being in contact with a
single reservoir of temperature and, in this way, is contradicting all
philosophy of actual thermodynamics. The yield of the entire process
is related to the background temperature of entire system, but this is
another story.
Of course, in practice such experiment can arrive to a yield of 90 to
95%, but from theoretical point of view there are no restrictions to
convert all heat into mechanical work.
It is quite difficult to have such piston and to cover an internal
wall with a layer of CO2 solid in order to not have a gas escape.
Therefore, in practical approach it can be used a box in box system
with an elastic membrane able to extend when internal box moves. Cost
of the experiment, in Romania conditions, less then 5000 euro. The
same experiment in developed west will arrive at few hundreds of
thousand euros. In fact I know people who refuted research contracts
of few hundreds of thousand Euros only because the documentation for
such project does not worth the effort. So, I will expect that such
research project will arrive to a price of few millions of euro, when
in fact the real cost is quite nothing.
Finally, it is proposed, like a curiosity, an engine working based on
solid carbon dioxide as combustible. Such engine, have to work on a 3
step cycle: feeding, expansion and evacuation. I think such engine
could have applications in space industry or even in Man to Mars
missions.
The link:
http://www.elkadot.com/ro/termodinamica/Combustia2.htm
As usual Romanian version is the reference. Further translations will
be provided.
I think I made an error in previous message. Theoreticians need half a
millennium to understand some experiments and not one or two centuries
as specified before. For understanding some new concepts, they need
even more time!
With or without their help the face of physics will be changed. In
fact, they have been becoming very expensive ballast into a race and
they need to be discarded!
The problem is, there is none to explain them the fact they are making
figuration and there is no mechanism to push them out of the well
warmed chairs where they are sitting spending money on nothing.
Best regards,
Sorin Cosofret

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