They aren't dangerous per se, but demand respect.   The failure modes are
extremely rare if you use quality cells and treat them well.   Proper BMS
is absolutely necessary!  Sadly I often find BMS-deniers that think it's
just not needed, you can read about a lot of fires from the "DIY powerwall"
people running w/o BMS.

Now that you can get a cheap and easy BMS, there's no excuse.

I think I'd be comfortable installing an LFP pack in a crawlspace, but I'd
build a box to house them.  You also want to constrain them on the large
faces so they can't swell anyway.  Constructing a box with a dryer vent
tube that leads outside would allow me to sleep well at night.

On Wed, Feb 25, 2026 at 12:15 AM DOOLEY PHILIP G JR <[email protected]>
wrote:

> LFP sounds much more dangerous than I had been led to believe.  I had been
> planning to put a used Calb LFP house backup battery in the insulated
> crawlspace under the airlock entryway.  However the floor above the cells
> is not airtight possibly gassing the escapees. I could just get another 8
> golf cart batteries to replace the old ones there that came from my first
> EV.  I had hoped to soon avoid crawling in there with a watering can.
> Connecticut climate spends a lot of time below freezing, do you have more
> info about charging LFP cells at or below freezing ? possibly slowly ?  Is
> water involved internally or do other chemicals have the same freezing
> point ?
>
> My first EV (a '93 escort electricar) now has a Trimetal Li battery giving
> a 30 mi range when above freezing and the '98 Solectria now has used coda
> LFP batteries.  Both have Orion BMS.
>
> I am working on assembling 2 ea 72AH 12V LFP batteries to replace the lead
> batteries for lighting.
>
> Phil Dooley
>
>
> On Tuesday, February 24, 2026 at 01:33:31 PM EST, (-Phil-) via EV <
> [email protected]> wrote:
>
>
> To be clear LFP is a shortened abbreviation of LiFePO₄.
>
> Yes, That was my conclusion too.  I have earlier video on it with more
> details:  https://www.youtube.com/watch?v=i27lApNWkyA  (Note: This was
> made
> 2 years ago before Tesla introduced the LFP version they are rolling out
> now)
>
> Indeed, Tesla is now using LFP in some models for the "12v" system.  LFP
> is "safer" than ternary; No doubt, and more tolerant of abuse.  If you are
> building any kind of home backup or battery storage that will be in or near
> your house, it's my opinion you should stick to LFP.  Those cells can still
> go into thermal runaway internally, but it usually doesn't spread to
> adjacent cells. (USUALLY!)
>
> HOWEVER, LFP can still have nasty failure modes that emit huge volumes
> (many orders of magnitude of the cell volume) of toxic gases that can
> easily kill you and/or cause an explosion if they are inside your house.
> So a large pack in your attached garage could easily kill you in your
> sleep even if just one large format cell goes off!  It should be in a
> sealed enclosure with a vent to the outside.  I've seen dryer vents used
> for this with the little metal flap, so it stays closed unless there is
> overpressure in the enclosure and then safely vents outside.  Another
> technique used is a foil seal.  You see this on the top of many large LFP
> cells.  The foil will burst and allow venting, but ensures the cell stays
> sealed in normal operation.  Since you cannot charge these cells below
> freezing, and they have a longer life if kept cool (i.e. They prefer to
> live in the same temperatures we do), it's tempting to install them inside.
>
> I personally have a ~9kWh LFP battery in my house using 16 of the Calb
> 180Ah cells in a 16S configuration. (~48V)  It's in an air-sealed enclosure
> with a vent fan that pulling air from outside through a filter and venting
> out the top to a vent stack on the roof.  I live in CA where I enjoy mild
> temperatures, so the pack stays pretty comfortable.  The fan is on a
> thermostat set for 80°F and this is located at the top near where the fan
> is.  I specifically chose a brushless fan and solid state thermostat to
> ensure there's no chance of ignition.  This fan/thermostat arrangement
> stops the air from getting too cold in the winter.  My BMS keeps the cell
> voltages from ever exceeding 3.4v and pack at or under 54v which is
> conservative. This reduces danger somewhat and greatly extends the life of
> the pack with only marginal reduction of capacity.  I have a monitor on
> the BMS that will send me a text if it ever goes too far off track, here's
> the current state:
> Overall pack: 54.0 V
> Highest Cell: 3.384 V (02)
> Lowest Cell:  3.375 V (10)
> Cell Delta:  0.009 V
> Battery Temp: 28 °C
>
> Note that regardless of cell quality, you should always expect an internal
> cell failure, it's rare, but does happen.  You should build your battery
> system as I did, with this failure in mind!
>
> Here's a copy/paste from an LFP safety analysis:
> "When a lithium iron phosphate (LFP or LiFePO₄) cell undergoes internal
> failure (e.g., due to an internal short circuit) or is externally shorted,
> it can lead to rapid heating, potentially triggering thermal runaway. This
> process causes the cell to vent gases through its safety valve or rupture
> points. These gases arise primarily from the decomposition of the organic
> electrolyte (e.g., carbonates like ethylene carbonate), breakdown of the
> solid electrolyte interphase (SEI) layer, and other internal reactions.
> The emitted gases include both flammable and toxic components, posing risks
> of fire, explosion (if accumulated gases reach ignition conditions in a
> confined space), and health hazards from inhalation.
>
> Main Dangerous Gases Emitted:
>
> 1. Hydrogen (H₂): Often the most abundant flammable gas (frequently 30–55%
> or more of the total vent gas volume, depending on conditions like state of
> charge). Highly flammable and explosive when mixed with air; contributes
> significantly to explosion risks.
>
> 2. Carbon monoxide (CO): Toxic and flammable (typically 8–28% range in
> studies). Colorless, odorless gas that causes asphyxiation by binding to
> hemoglobin; a major toxicity concern.
>
> 3. Carbon dioxide (CO₂): Non-flammable but can displace oxygen and
> contribute to asphyxiation in high concentrations (often 15–36%).
>
> 4. Hydrocarbons (e.g., methane CH₄, ethylene C₂H₄, ethane C₂H₆, propylene
> C₃H₆): Flammable and present in smaller but significant amounts (combined
> often 5–15%). These lower the ignition energy and widen the flammability
> range of the gas mixture.
>
> 5. Hydrogen fluoride (HF): Extremely toxic and corrosive gas (produced from
> decomposition of the LiPF₆ salt in the electrolyte and fluorinated
> binders). Forms hydrofluoric acid in moist air or when water is applied
> (e.g., during firefighting); causes severe respiratory damage, skin burns,
> and systemic toxicity even at low concentrations. LFP cells can produce
> notable amounts of HF, sometimes more than other chemistries under certain
> conditions."
>
> On Tue, Feb 24, 2026 at 7:55 AM Mark Hanson via EV <[email protected]>
> wrote:
>
> > Hi Phil etc
> > That’s very interesting that just normal charging ternary NMC cells that
> > are dead at/below 2V per cell can cause a fire due to dendrite growth
> > shorting out the plates.
> > Your video showed Tesla using these cells in their 12v aux batteries on
> > new EVs.  Sounds like Tesla screwed up and should use LFP cells for 12v
> > battery replacements like everyone else
> > Do LFP batteries have the same problem if a dead cell <2V per cell is
> > normally charged?  I’m sure I’ve done this in the past with LiFePo4 cells
> > without thinking about it (mostly small battlebots).  Don’t recall
> running
> > into this when I used to convert EVs using Calb or Thundersky LFP cells
> > (since EVs didn’t sit to long without being charged)
> > Stay Charged,
> > Mark
> > Sent from my iPhone
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