After some more googling and looking it appears that you will be able to run 
DCPROMO and it will remove the DC. But then all hell is going to break loose in 
your Exchange system. CAS is going to be broken along with OWA authentication.

Sorry man, but you really need to migrate the exchange off that box first.



From: Kennedy, Jim [mailto:[email protected]]
Sent: Friday, August 21, 2009 1:01 PM
To: MS-Exchange Admin Issues
Subject: RE: demoting DC with Exchange 07


I am not sure you are even going to be able to run DCPROMO, though I have never 
tried it. I think you may have to migrate Exchange off of it first.



Installing Exchange 2007 on Directory Servers



For security and performance reasons, we recommend that you install Exchange 
2007 only on member servers, and not on Active Directory directory servers. 
Although installing Exchange 2007 on a directory server is supported, it is 
strongly discouraged. However, you cannot run DCPromo on a computer running 
Exchange 2007. After Exchange 2007 is installed, changing its role from a 
member server to a directory server, or vice versa, is not supported.



http://technet.microsoft.com/en-us/library/aa996719.aspx





-----Original Message-----

From: James Kerr [mailto:[email protected]]

Sent: Friday, August 21, 2009 11:49 AM

To: MS-Exchange Admin Issues

Subject: demoting DC with Exchange 07



I need to demote a 08 server DC that is also running exchange 07 this

weekend. Any gotchas I need to worry about or should just be a standard

demotion

event? The other DCs are all 03 servers, don't think that complicates

anything.



Thanks,



James








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