This is not a request for help but a report, in case it helps developers or someone in the future. The setup is:

AMD64 machine, 24 GB RAM, 2x6-core Xeon CPU + HTT (24 logical CPUs)
FreeBSD 8.1-stable, AMD64
PostgreSQL 9.0.1, 10 GB shared buffers, using pgbench with a scale factor of 500 (7.5 GB database)

with pgbench -S (SELECT-queries only, no disk IO) the performance curve is:

-c#     result
4       33549
8       64864
12      79491
16      79887
20      66957
24      52576
28      50406
32      49491
40      45535
50      39499
75      29415

After 16 clients (which is still good since there are only 12 "real" cores in the system), the performance drops sharply, and looking at the processes' state, most of them seem to eat away system call (i.e. executing in the kernel) in states "semwait" and "sbwait", i.e. semaphore wait and socket buffer wait, for example:

 3107 pgsql       1  62    0 10533M   439M CPU1    0   0:02 13.57% postgres
 3105 pgsql       1  63    0 10533M   438M CPU9    9   0:02 13.57% postgres
 3109 pgsql       1  62    0 10533M   440M sbwait 13   0:02 13.48% postgres
 3106 pgsql       1  61    0 10533M   445M sbwait  8   0:02 13.48% postgres
 3118 pgsql       1  62    0 10533M   431M sbwait 21   0:02 13.48% postgres
 3114 pgsql       1  63    0 10533M   434M sbwait 19   0:02 13.38% postgres
 3122 pgsql       1  63    0 10533M   428M sbwait 15   0:02 13.28% postgres
 3108 pgsql       1  63    0 10533M   439M sbwait  5   0:02 13.18% postgres
 3116 pgsql       1  62    0 10533M   432M sbwait 11   0:02 13.18% postgres
 3113 pgsql       1  62    0 10533M   430M semwai 20   0:02 13.18% postgres
 3115 pgsql       1  62    0 10533M   428M RUN    14   0:02 13.18% postgres

The "semwait" part is from PostgreSQL - probably shared buffer locking, but there's a large number of processes regularly in sbwait - maybe something can be optimized here?

This is IPC over Unix sockets.

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