correction,  H2 molecules
  ----- Original Message ----- 
  From: Mark Ludlow 
  To: 'Leland T Taylor' ; 'Discussion of biomass pyrolysis and gasification' 
  Sent: Saturday, March 05, 2011 10:45 PM
  Subject: Re: [Gasification] sidebar Ideal Gas Law for engineering


  …and the phenomenon of diffusion. It’s not a theoretical impossibility, 
either, given several thousand ultra-high-speed gas centrifuges cascaded 
together.

   

  From: [email protected] 
[mailto:[email protected]] On Behalf Of Leland T 
Taylor
  Sent: Saturday, March 05, 2011 9:53 PM
  To: Discussion of biomass pyrolysis and gasification
  Subject: Re: [Gasification] sidebar Ideal Gas Law for engineering

   

  Except for the moving atmosphere, thermal effects of circulation etc.
  Tom Taylor




  -- Sent from my Palm Pixi

   


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  On Mar 5, 2011 8:08 PM, Mark Ludlow <[email protected]> wrote: 

  Hi Toby,

  I think I see what you mean by the “balloons”. So I would ask this question: 
“If a mixture of gases (as represented by the ‘normal’ Earth’s atmosphere) 
would stratify as you suggest, wouldn’t one expect the atmosphere to have a 
different composition at every discrete altitude?” Or: “Wouldn’t all the CO2 
have suffocated us by now, even if it is only 0.035% of the atmosphere? (If the 
atmosphere were 100,000 ft thick, that would still be 35-feet.)”

   

  Intended to be a thought experiment. Sometimes though experiments can save 
time and money.

  Best regards, Mark

   

  From: [email protected] 
[mailto:[email protected]] On Behalf Of Toby Seiler
  Sent: Saturday, March 05, 2011 3:54 PM
  To: [email protected]
  Subject: [Gasification] sidebar Ideal Gas Law for engineering

   

        Daniel and all,

         

        That's a great explanation and helps a lot.  I see the proportionality 
in relation to absolute pressure and temperature.  It validates use of an 
inter-cooler and away from heated incoming air, even into ones gasifier, I 
believe, as far as putting oxygen into the device.  

         

        I'm speculating here, but thinking of making and trying an oxygen 
enhancing low pressure system, from lots of long tubular balloons? Oxygen, 
being a slight bit lighter than nitrogen, could be taken from the low point, 
and since under pressure, have some portion of the rejected nitrogen and 
combined air-nitrogen discharged through an orifice at the high point.  

         

        I see at the end of your post that air, with gasoline fuel at 12-1 and 
15-1 ratio, has 2.4 and 3 lbs of oxygen per pound of fuel respectfully 
(rounding to 20% O/air).   Isn't the target ratio of producer gas to oxygen one 
to one in an IC engine?  Or is that 1lb air, thus 1/5 the oxygen or a 5-1 ratio 
for producer gas to air?  The car guys are generally using a 50% air and 50% 
producer gas ratio, which would seem to validate the 5-1 ratio of gas to oxygen 
by weight. 

         

        I'm sure with the numbers you provided I can figure flow rates at each 
stage.  I will verify my flow so sizing is correct before cutting/welding.   I 
purchased some 4" and 6" dia 304 stainless pipe at a salvage company and have a 
SS air tank for some of the hot section heat recovery from the second stage 
reactor (and I think enough for a steam superheater... part of final gas 
cooling).   

         

        Gas out starts at about 1800f from the x-flow reactor, as gas from 
stage one is burned and reformed into synthesis gas going through the char bed. 
 The gas outlet is direct coupled to the heat recovery, flowing first to heat 
stage one incoming fuel, then to a steam superheater and then to a water 
boiler.  It's a CHP arrangement, since massive amounts of heat have to be 
removed in prooducer-synthesis (prosyn) gas cooling.    

         

        Thanks for your explanation.  Mole remains a small fuzzy creature.

         

        Toby 

        Seilertechco

         

          

         

         
       

   



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