>From my memories of synthesizing music and testing equipt the square wave 
was always harsh and moreso was the sawtooth. 
Fast wavefrronts and sharp peaks are unhappy companions to the ear- so even 
if nothing worse is contained in hum, distortions can easily be picked up 
and discordant to the human ear.
The 'deisel' sound of hum with a hunting tendency must have many harmonics 
on the non sinusoidal front which will contribute to aural discomfort, 
without doubt.

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