Hi Kris

I'm no expert in Linux, but it seems that your system doesn't know 
how to open jar files. So, you must invoke Java for that file:

   java -jar Jmol.jar

adding the proper paths to java and Jmol.jar, if needed

Another option is to try the script file included in the 
distribution, which for your system should be
  jmol
or
  jmol.sh
that is supposed to have the proper parameters, but you probably have 
to tweak it a bit

Let us know if you find the solution (or not)



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