James,

It does not make much sense to me, as you think too.
I agree it should not be a Java path problem.

Maybe: since Jmol is not installed, but just copied, try to check 
what the permissions are on the Jmol.jar file and folder. It may 
belong to one user and the other not have ful permissions (a very 
wild guess)

I would think as you that two administrators have the same 
permissions, but Win7 and Win8 are giving me signals to the contrary: 
e.g. being an admin user I cannot overwrite some files (from within a 
program) that I created but maybe I have moved back and forth between 
computers --cannot make any sense of this, but things seem to be more 
complex that plain user rights.

You could also try to extract a 2nd copy of Jmol.jar from the 
distribution while beiong the problematic user and see what happens.

Good luck

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