Detonation is more the cracked piston route which can be

Diesels don't detonate, which is a flame front running
faster than the speed of sound in the medium.  (If I recall
correctly.)  Diesel fuel is sprayed into a hot chamber,
and burns as it goes in.  Late-coming fuel doesn't find
any oxygen to bind with nearby, and so travels further
until it does.  It's a _very_ different combustion cycle
than an Otto.

The injector spray pattern is crucial, because you want
the fuel to be well mixed and sprayed around so that it
burns where it is supposed to, in the middle, rather than
up against the piston directly.

The same basic principles of stochastic mixture apply in Diesel
engines. So if you 'pump' in more air you will need more fuel.

No, they do not.  Stoichiometric ratios might determine how
clean-burning the engine was, but not how much power you got.
You don't need to supply fuel to match all the air.  That's
the whole point of a diesel, and one of the big reasons they
get better fuel economy in general.  Apparently you can over-
fuel a diesel and get more power, but at diminishing returns.
Until you quench the thing entirely.  See the smoke-belching
monster diesel trucks.  Those engines don't last long, but
what do you expect with 60# of boost and 1200+ horses out of
a rated 300 horse motor?  (For example.)

As I attempted to explain earlier, it is the amount of air being
compressed that determines temperatures.  The amount of fuel does
not influence temperature

Pre-ignition, yes.  Once flame enters the picture that's not
true, and the situation gets complicated.  PV=nRT only where
there aren't chemical (or other) reactions polluting the pool.

Diesels don't have 'mixture'.  The only mixture is determined
by how good the spray pattern is.  (And combustion chamber design.)
They get less power per displacement (ceterus paribus) because they're
not as efficient at using up the last of the air.  They get better
economy because they're not constrained to stoichiometric ratios
in order to prevent detonation and too-high pressures (i.e. too-hot
chambers) because lean _mixtures_ burn faster (and therefore hotter
in a chamber that's not expanding fast enough to absorb the heat
energy and convert it to mechanical energy.  (Diesel also has somewhat
more BTU/gallon, so that helps the economy figures a little, but
not enough to explain away the observed differences.)

If the motion of the piston can't suck away the heat fast enough
and convert it to work, that heat will go into melting the piston
instead.  Any particular engine design will have a sweet spot where
its burn rate has the optimum power extracted at some particular RPM
and load.  They'll vary.

I find heat engine design theory fascinating.

-- Jim



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