You are an engineer, aren't you?  I can smell them -- my son is one.

On 6/26/06, Peter Frederick <[EMAIL PROTECTED]> wrote:

Actually, viscosity ratings are more complicated.  In the old days, you
have an oil of a particular viscosity (actually flow rate at a certain
temperature).  Petroleum based oils have a significant change of
viscosity with change in temperature character -- when hot, they get
VERY thin.  When cold, of course, they aquire the flow characteristics
of molassas, what ever the room temperature viscosity.

The solution was to add materials that didn't change viscosity so much,
so that an oil mixture would have "multi-viscosity" characteristics --
that is, flow like say a 10 wt oil cold and a 30 wt oil hot.  The
rating is cold viscosity rating number first, followed by hot viscosity
rating, so a 10W-40 oil flows like a single rating 10W oil cold and
like a single rating 40W hot.

The base fluid used in synthetic oils doesn't change viscosity with
temperature nearly as much as petroleum base oils, and in fact is
fairly hard to rate using methods for petroleum base oils.  0W-30
synthetic oil pours like cold diesel fuel, but I'd not want to use
diesel fuel as an engine oil -- wouldn't stay in the engine!

The smaller molecules will likely burn off first, since they are more
volatile, but I suspect there really aren't that many in synthetic oil.
  The majority of oil consumption in a good condition engine is burnoff
from the cylinder walls as they are exposed during combustion, along
with whatever amount burns off the valves from clearance on the stems.
Synthetics are very resistant to oxidation (remember the frying pan on
the grill ads?)  so they don't burn off the cylinder walls, and the
molecules are fairly large so they won't evaporate.  No modern oil has
components light enough to actually vaporize, I would venture -- they
would also carbonize too easily, leading to excessive sludge.

What the viscosity of a mixture is would be hard to determine without
actually testing it, and I suspect what you would have would be xxW-50
-- the viscosity "extenders" would work their magic more at the hot end
than the cold end.

Fun stuff, eh?  No wonder oil threads go on forever!

Peter


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