Hi Kiat, 

when your peptide has a free amino group (N-terminal and/or lysine), it's easy:

There's a lot of reactive molecules available (eg Biotin, for immobilizing your 
peptide to streptavidin-beads (good for immunoprecipitation), various 
fluorescent labels for microscopy etc etc.

The chemistry behind is simple: You may obtain the labels als NHS (N-hydroxy 
succinimde) esters (, sometimes also abbreviated -OSu, e.g. from Sigma, Pierce 
(Thermo), Molecular Probes (Invitrogen)); just dissolve them in a bit of dry 
DMSO or DMF and couple for 2hrs in an alkaline buffer (eg 100mM Borate, pH 
8.5). 

To discuss details or other options (eg the amino group should not be labeled), 
please post your structure and what you need the label for.

HTH

Wo
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