Thanks to everyone for the responses. That Qiagen article was surprisingly
helpful, though it would be nice for them to share the constitution of their
"Q Solution".

In particular I was interested to read about the ammonium ion effects and
the effects of high temperatures; the high-temperature depurination issue
may have been behind some past PCR failures of mine. Good to know!

Thanks again,
Cathal

On 10 July 2011 15:28, chovek69 <[email protected]> wrote:

> On Jul 8, 3:16 pm, [email protected] (DK) wrote:
> > In article <
> 740568f1-764d-4381-aa90-15b203e79...@x41g2000yqd.googlegroups.com>,
> chovek69 <[email protected]> wrote:
> >
> > >I regularly amplify >3kb with regular Taq with (NH4)2SO4 buffer (see
> > >link below) + 1M Betaine and 5min extension step at 65C.
> >
> > >http://www.whitelabs.org/Lab%20Protocols/PCR%20Protocols/kyle.htm
> >
> > Just curious: why 65C? 5 min total extension for 3 kbp or per every kbp?
> >
> > Thanks,
> >
> > DK
>
> It is 65C for 5min total ext time and betaine is critical.
>
> There are some reports stating that decreasing extension and
> denaturation temp could improve long PCR. See for example this
> http://www.qiagen.com/literature/qiagennews/0398/983pcro.pdf
> although there many others.
>
> I think it is because of the damage to the template during the longer
> cycles plus betaine could decrease the Tm a degree or two. Of course
> the the amplicon  %GC  is most important for the optimal ext temp so
> it is best to run a gradient optimization.
>
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