Thanks for your reply! 

I tried it with version 0.19.0, 0.20.0 and 0.21.0

IP address is 100% correct configured in the Gsuite relay settings.
I can connect from command line as you mentioned and I can send mails from 
this host with local postfix using smtp-relay.gmail.com as relayhost.

[email protected] schrieb am Dienstag, 29. September 2020 um 11:07:12 UTC+2:

> Alertmanager version?
>
> Try logging into the same host where alertmanager runs, and running the 
> following:
>
> openssl s_client -connect smtp-relay.gmail.com:587 -starttls smtp
> ehlo mydomain.com
> mail from:<[email protected]>
>
> See if you get an error like this:
>
> 550-5.7.0 Mail relay denied [<address>]. Invalid credentials for
> 550-5.7.0 relay for one of the domains in: mydomain.com (as obtained from 
> HELO and
> 550-5.7.0 MAIL FROM).
> 550-5.7.0 Email is being sent from a domain or IP address which isn't 
> registered
> 550-5.7.0 in your G Suite account. Please login to your G Suite account and
> 550-5.7.0 verify that your sending device IP address has been registered 
> within
> 550-5.7.0 the G Suite SMTP Relay Settings. For more information, please 
> visit
> 550 5.7.0  https://support.google.com/a/answer/6140680#maildenied
>
> One possibility is that your host has gained a new external IP address (on 
> IPv6 perhaps?) which has not been registered.
>

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