While the availability of the scattering factor for B3+ is certainly a novelty 
(at least for me), one should be aware that, even in BF4 (where highly 
electronegative F atoms are bound to Boron), the bonding is mostrly covalent, 
and may contain a non-negligible contribution of pi-pi backdonation.
This said, modeling BF4 from scattering data is a difficult task, as non 
harmonic adps  and disorder often dominate.
Norberto

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________________________________
From: [email protected] <[email protected]> on behalf of Le 
Bail Armel <[email protected]>
Sent: Saturday, March 22, 2025 7:57:27 PM
To: Matthew Rowles <[email protected]>
Cc: Rietveld List ([email protected]) <[email protected]>
Subject: Re: B3+


Thanks a lot !

Armel

envoyé : 22 mars 2025 à 17:26
de : Matthew Rowles <[email protected]>
à : Luca Lutterotti <[email protected]>
cc : Le Bail Armel <[email protected]>, "Rietveld List 
([email protected])" <[email protected]>
objet : Re: B3+


Try https://onlinelibrary.wiley.com/iucr/doi/10.1107/S2053273323010550

And

https://journals.iucr.org/paper?ae5125

Matthew

On Thu, 20 Mar 2025, 15:47 Luca Lutterotti, 
<[email protected]<mailto:[email protected]>> wrote:
Nope, I checked what I have and I use Xraylib now in Maud but also there is 
only B neutral. Maybe someone can calculate them?

Ciao Luca


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Luca Lutterotti
Dipartimento di Ingegneria Industriale
Università di 
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On 19 Mar 2025, at 20:58, Le Bail Armel 
<[email protected]<mailto:[email protected]>> wrote:


Hello,

Any parametrized X-ray scattering factor for B3+ somewhere ?

A case with [BF4] tetrahedra.

Thanks !

Armel

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